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The new edition of this classic textbook desrcibes the physical and organic chemistry of the reactions that produce polymers. Three primary features distinguish this book from the competition: 1) each topic is prefaced with a thorough discussion at the elementary level, assuming at most only some background in physical and organic chemistry; 2) the presentation and writing are geared for the student; 3) each topic is subsequently considered at an advanced level, allowing both the novice and more accomplished student to achieve an advanced understanding of polymer synthesis.