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This book highlights a novel and holistic approach to multiscaled PVA bionanocomposite films usedfor electrical sensing, medical and packaging applications. With a combination of material characterization and modeling to understand the effect of nanoparticle size and shape, as well as 3D interphase properties and features such as interphase modulus and nanoscale dimensions,this book explores how the excellent mechanical and thermal properties of these materials are achieved. Alsoit addressesthe importance of using economical and ecofriendly bionanocomposites as potentialgreen materials to support the goal of environmental sustainabilitywith multifunctional properties.