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The VI International Conference on Times of Polymers (TOP) and Composites was held on June 2012 (Ischia-Italy). This was the fourth of a series of biennial workshops on polymers timescales resulting from a joint initiative of the Second University of Naples-SUN and the University of Naples Federico II. Scientists from chemistry to physics to engineering areas formed a homogeneous community as the contributions, even if spanning on very different topics, subtend the concept of timescale of polymer based materials.